Iron and steel

Ferrous metallurgy is the metallurgy of iron and its alloys. The earliest surviving prehistoric iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. t is not known when or where the smelting of iron from ores began. The use of wrought iron (worked iron) was known by the 1st millennium BC, and its spread defined the Iron Age. During the medieval period, smiths in Europe found a way of producing wrought iron from cast iron, in this context known as pig iron, using finery forges. All these processes required charcoal as fuel.

By the 4th century BC southern India had started exporting wootz steel, with a carbon content between pig iron and wrought iron. Archaeological evidence of cast iron appears in 5th-century BC China. New methods of producing it by carburizing bars of iron in the cementation process were devised in the 17th century. During the Industrial Revolution, new methods of producing bar iron emerged, by substituting charcoal in favor of coke, and these were later applied to produce steel, ushering in a new era of greatly increased use of iron and steel that some contemporaries described as a new "Iron Age".

In the late 1850s Henry Bessemer invented a new steelmaking process which involved blowing air through molten pig-iron to burn off carbon, and so producing mild steel. This and other 19th-century and later steel-making processes have displaced wrought iron. Today, wrought iron is no longer produced on a commercial scale, having been displaced by the functionally equivalent mild or low-carbon steel.